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BENZYL ETHYL ETHER
Benzyl ethyl ether (CAS 539-30-0) is a versatile aromatic ether engineered for organic synthesis, protecting group chemistry, and specialty solvent applications. This molecule integrates a benzyl moiety—a benzylic carbon with enhanced reactivity toward radical or electrophilic processes—with an ethyl ether linkage, creating a stable yet functionally tunable architecture. The benzylic C–H bonds are susceptible to selective oxidation or halogenation, enabling downstream diversification to compounds such as benzaldehyde and benzyl alcohol. As a protecting group precursor, benzyl ethyl ether can be cleaved under hydrogenolytic or Lewis acidic conditions to release benzyl-protected alcohols, making it valuable for orthogonal deprotection strategies in complex molecule synthesis. It is also recognized as a food-grade flavoring agent (FEMA 2144) with a powerful, fruity aroma, found naturally in cocoa and used in fragrance applications. This intermediate is particularly valuable for constructing pharmaceutical intermediates, fragrance compounds, and polymer additives where the benzyl-ether motif balances stability with controlled reactivity. Manufactured under controlled conditions, it supports synthetic programs requiring reliable ether solvents or benzylating reagents with well-defined physicochemical properties.
Property
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Product Name
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Benzyl ethyl ether
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CAS Number
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539-30-0
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Chinese Name
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苄基乙基醚
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Synonyms
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Ethoxy(methyl)benzene; (Ethoxymethyl)benzene; Benzyl ethyl ether; Ethoxymethylbenzene
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Chinese Synonyms
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乙氧基甲基苯; 苄基乙基醚; 乙基苄基醚; 苯甲氧基乙烷
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Molecular Formula
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C₉H₁₂O
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Molecular Weight
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136.19 g/mol
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Purity
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≥ 98% (GC area normalization)
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Product Category
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Fine Chemicals / Organic Solvents / Benzyl Ether Derivatives
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Appearance
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Colorless to Pale Yellow Liquid
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Boiling Point
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~185-190°C at 760 mmHg (literature)
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Density
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~0.96 g/cm³ at 20°C (estimated)
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Refractive Index
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n₂₀/D ~1.49 (estimated)
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Flash Point
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~65-70°C (closed cup, estimated)
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Storage Conditions
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Store in a cool, dry, well-ventilated area away from light and moisture. Keep container tightly closed under inert atmosphere (nitrogen). Protect from strong oxidizing agents and acids to avoid ether cleavage or benzylic oxidation.
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Shelf Life
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24 months under recommended storage conditions
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Packaging
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100g/bottle, 500g/bottle, 1kg/bottle, 5kg/drum, or customized according to customer requirements (amber glass recommended for light-sensitive batches)
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Applications
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Organic synthesis solvent, benzyl protecting group reagent, fragrance/intermediate synthesis, polymer additive precursor, phase-transfer catalysis medium, benzylic functionalization studies
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Reactivity
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Suitable for benzylic bromination/oxidation, ether cleavage (HI, BBr₃), hydrogenolysis (Pd/C, H₂), electrophilic aromatic substitution on phenyl ring, and use as inert solvent for organometallic reactions
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Special Note
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✅ Benzylic Ether Scaffold—benzylic C–H enables selective functionalization; ether linkage provides stability. Flammable liquid—handle away from ignition sources. Part of our benzyl ether building block series.
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