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BENZYL ETHYL ETHER

Benzyl ethyl ether (CAS 539-30-0) is a versatile aromatic ether engineered for organic synthesisprotecting group chemistry, and specialty solvent applications. This molecule integrates a benzyl moiety—a benzylic carbon with enhanced reactivity toward radical or electrophilic processes—with an ethyl ether linkage, creating a stable yet functionally tunable architecture. The benzylic C–H bonds are susceptible to selective oxidation or halogenation, enabling downstream diversification to compounds such as benzaldehyde and benzyl alcohol. As a protecting group precursor, benzyl ethyl ether can be cleaved under hydrogenolytic or Lewis acidic conditions to release benzyl-protected alcohols, making it valuable for orthogonal deprotection strategies in complex molecule synthesis. It is also recognized as a food-grade flavoring agent (FEMA 2144) with a powerful, fruity aroma, found naturally in cocoa and used in fragrance applications. This intermediate is particularly valuable for constructing pharmaceutical intermediates, fragrance compounds, and polymer additives where the benzyl-ether motif balances stability with controlled reactivity. Manufactured under controlled conditions, it supports synthetic programs requiring reliable ether solvents or benzylating reagents with well-defined physicochemical properties.

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Product Name
Benzyl ethyl ether
CAS Number
539-30-0
Chinese Name
苄基乙基醚
Synonyms
Ethoxy(methyl)benzene; (Ethoxymethyl)benzene; Benzyl ethyl ether; Ethoxymethylbenzene
Chinese Synonyms
乙氧基甲基苯; 苄基乙基醚; 乙基苄基醚; 苯甲氧基乙烷
Molecular Formula
C₉H₁₂O
Molecular Weight
136.19 g/mol 
Purity
≥ 98% (GC area normalization)
Product Category
Fine Chemicals / Organic Solvents / Benzyl Ether Derivatives
Appearance
Colorless to Pale Yellow Liquid
Boiling Point
~185-190°C at 760 mmHg (literature)
Density
~0.96 g/cm³ at 20°C (estimated)
Refractive Index
n₂₀/D ~1.49 (estimated)
Flash Point
~65-70°C (closed cup, estimated)
Storage Conditions
Store in a cool, dry, well-ventilated area away from light and moisture. Keep container tightly closed under inert atmosphere (nitrogen). Protect from strong oxidizing agents and acids to avoid ether cleavage or benzylic oxidation.
Shelf Life
24 months under recommended storage conditions
Packaging
100g/bottle, 500g/bottle, 1kg/bottle, 5kg/drum, or customized according to customer requirements (amber glass recommended for light-sensitive batches)
Applications
Organic synthesis solvent, benzyl protecting group reagent, fragrance/intermediate synthesis, polymer additive precursor, phase-transfer catalysis medium, benzylic functionalization studies
Reactivity
Suitable for benzylic bromination/oxidation, ether cleavage (HI, BBr₃), hydrogenolysis (Pd/C, H₂), electrophilic aromatic substitution on phenyl ring, and use as inert solvent for organometallic reactions
Special Note
Benzylic Ether Scaffold—benzylic C–H enables selective functionalization; ether linkage provides stability. Flammable liquid—handle away from ignition sources. Part of our benzyl ether building block series.