7-Diethylamino-3-thenoylcoumarin
7-Diethylamino-3-thenoylcoumarin (CAS 77820-11-2) is a high-performance fluorescent coumarin derivative engineered for laser dye applications, optoelectronic materials, and biological imaging. This molecule integrates a 7-diethylaminocoumarin core—a privileged fluorophore scaffold known for high quantum yield and photostability—with a 3-thenoyl substituent containing a sulfur-bearing thiophene ring. The introduction of the thenoyl group at the C3 position extends the π-conjugation system, resulting in red-shifted absorption and emission profiles compared to standard 3-acylcoumarins, while the diethylamino donor at C7 enhances intramolecular charge transfer (ICT) efficiency. This intermediate is particularly valuable for constructing tunable laser dyes, fluorescent probes for protein labeling, and organic light-emitting diode (OLED) materials where sulfur-heterocycle integration modulates electronic properties and solvatochromic behavior. Manufactured with purity ≥98-99% under controlled conditions, it supports research programs requiring precise wavelength control and robust fluorescence performance in complex media.
Property
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Product Name
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7-Diethylamino-3-thenoylcoumarin
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CAS Number
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77820-11-2
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Chinese Name
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7-二乙氨基 -3-噻吩甲酰基香豆素
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Synonyms
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Coumarin dye 77820-11-2; 3-(2-Thenoyl)-7-diethylaminocoumarin; C₁₈H₁₇NO₃S fluorescent dye; Laser dye intermediate
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Chinese Synonyms
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3-(2-噻吩甲酰基)-7-二乙氨基香豆素; 二乙氨基噻吩甲酰香豆素; 香豆素激光染料; 荧光标记中间体
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Molecular Formula
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C₁₈H₁₇NO₃S
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Molecular Weight
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327.40 g/mol
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Purity
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≥ 98% (HPLC area normalization)
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Product Category
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Fine Chemicals / Fluorescent Dyes / Coumarin Derivatives
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Appearance
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Yellow to Orange to Red-Orange Crystalline Powder |
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Melting Point
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~180-185°C (estimated, literature reference recommended)
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MDL Number
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MFCD00183224
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Storage Conditions
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Store in a cool, dry place away from light. Use amber glass containers under inert atmosphere (nitrogen). Protect from strong oxidizing agents.
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Shelf Life
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24 months under recommended storage conditions (monitor for photodegradation)
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Packaging
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100mg/vial, 500mg/vial, 1g/bottle, 5g/bottle, or customized according to customer requirements
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Applications
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Tunable laser dye synthesis, fluorescent probe development, biological staining (protein/DNA), OLED material precursor, solvatochromic sensor design, optoelectronic research
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Reactivity
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Suitable for further functionalization at the thiophene ring, ester/amide modification (if applicable), incorporation into polymer matrices, and solvent-dependent fluorescence tuning
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Special Note
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✅ Sulfur-Extended Fluorophore—Thenoyl group provides red-shifted emission vs. benzoyl analogs. Light-sensitive—store in amber containers to prevent photobleaching. Part of our fluorescent dye building block series.
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