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7-Diethylamino-3-thenoylcoumarin

7-Diethylamino-3-thenoylcoumarin (CAS 77820-11-2) is a high-performance fluorescent coumarin derivative engineered for laser dye applicationsoptoelectronic materials, and biological imaging. This molecule integrates a 7-diethylaminocoumarin core—a privileged fluorophore scaffold known for high quantum yield and photostability—with a 3-thenoyl substituent containing a sulfur-bearing thiophene ring. The introduction of the thenoyl group at the C3 position extends the π-conjugation system, resulting in red-shifted absorption and emission profiles compared to standard 3-acylcoumarins, while the diethylamino donor at C7 enhances intramolecular charge transfer (ICT) efficiency. This intermediate is particularly valuable for constructing tunable laser dyesfluorescent probes for protein labeling, and organic light-emitting diode (OLED) materials where sulfur-heterocycle integration modulates electronic properties and solvatochromic behavior. Manufactured with purity ≥98-99% under controlled conditions, it supports research programs requiring precise wavelength control and robust fluorescence performance in complex media.

Property

Product Name
7-Diethylamino-3-thenoylcoumarin
CAS Number
77820-11-2
Chinese Name
7-二乙氨基 -3-噻吩甲酰基香豆素
Synonyms
Coumarin dye 77820-11-2; 3-(2-Thenoyl)-7-diethylaminocoumarin; C₁₈H₁₇NO₃S fluorescent dye; Laser dye intermediate
Chinese Synonyms
3-(2-噻吩甲酰基)-7-二乙氨基香豆素; 二乙氨基噻吩甲酰香豆素; 香豆素激光染料; 荧光标记中间体
Molecular Formula
C₁₈H₁₇NO₃S
Molecular Weight
327.40 g/mol
Purity
≥ 98% (HPLC area normalization)
Product Category
Fine Chemicals / Fluorescent Dyes / Coumarin Derivatives
Appearance
Yellow to Orange to Red-Orange Crystalline Powder
Melting Point
~180-185°C (estimated, literature reference recommended)
MDL Number
MFCD00183224
Storage Conditions
Store in a cool, dry place away from light. Use amber glass containers under inert atmosphere (nitrogen). Protect from strong oxidizing agents.
Shelf Life
24 months under recommended storage conditions (monitor for photodegradation)
Packaging
100mg/vial, 500mg/vial, 1g/bottle, 5g/bottle, or customized according to customer requirements
Applications
Tunable laser dye synthesis, fluorescent probe development, biological staining (protein/DNA), OLED material precursor, solvatochromic sensor design, optoelectronic research
Reactivity
Suitable for further functionalization at the thiophene ring, ester/amide modification (if applicable), incorporation into polymer matrices, and solvent-dependent fluorescence tuning
Special Note
Sulfur-Extended Fluorophore—Thenoyl group provides red-shifted emission vs. benzoyl analogs. Light-sensitive—store in amber containers to prevent photobleaching. Part of our fluorescent dye building block series.